Jan 2015 - Article in Synlett Published
James' paper on the Organocatalytic Phosphorylation of Alcohols Using Pyridine-N-oxide is published.
James I. Murray, Rudiger Woscholski and Alan C. Spivey* Organocatalytic Phosphorylation of Alcohols Using Pyridine-N-oxide, Synlett, 2015, ASAP. DOI:
Phosphorylation of alcohols by phosphoryl chlorides catalysed by pyridine-N-oxide is reported. The utility of this method is demonstrated through phosphorylation of primary, secondary and a tertiary alcohol as well as phenols under mild reaction conditions and with low catalyst loading (5 mol%).
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Professor Alan C Spivey
Department of Chemistry